Comparative Adsorption Performance of Coconut Coir and Coconut Coir-Derived Activated Carbon toward Chromiums Ions
DOI:
https://doi.org/10.52434/npcb.v1i2.43288Keywords:
activated carbon, coconut coir, Cr(VI), Cr(III), cdsorption capacityAbstract
Chromium contamination in aqueous systems commonly occurs as Cr(VI) and Cr(III), both of which pose environmental risks. This study comparatively evaluates the adsorption performance of raw coconut coir and sulfuric acid-activated carbon derived from coconut coir toward chromium ions. Activated carbon was characterized according to SNI 06-3730-1995 based on moisture and ash content, and adsorption capacity was determined using Atomic Absorption Spectrophotometry at an initial concentration of 50 ppm and pH 2. Raw coconut coir exhibited no measurable adsorption capacity for either Cr(VI) or Cr(III). In contrast, the activated carbon demonstrated adsorption capacities of 14.677 ± 0.367 mg/g for Cr(VI) and 26.923 ± 0.370 mg/g for Cr(III), with corresponding removal efficiencies of 29.355 ± 0.750% and 53.846 ± 0.739%, respectively. The adsorption capacity for Cr(III) was approximately 1.8 times higher than that for Cr(VI), indicating stronger interactions between cationic chromium species and oxygen-containing functional groups on the activated carbon surface. These findings confirm that sulfuric acid activation substantially enhances the adsorption capability of coconut coir, particularly for Cr(III) removal under acidic conditions.
References
Ambika, S., Kumar, M., Pisharody, L., Malhotra, M., Kumar, G., Sreedharan, V., Singh, L., Nidheesh, P. V., & Bhatnagar, A. (2022). Modified biochar as a green adsorbent for removal of hexavalent chromium from various environmental matrices: Mechanisms, methods, and prospects. Chemical Engineering Journal, 439(January). https://doi.org/10.1016/j.cej.2022.135716
Che Ismail, N. H., Zurizam, N. A. F., & Hashim, F. (2025). Performance of Activated Carbon from Cassava Peel for the Removal of Pb(II) in Pb Solution. Journal of Academia, 13(1), 34–42. https://doi.org/10.24191/joa.v13i1.4582
Deng, Z., Sun, S., Li, H., Pan, D., Patil, R. R., Guo, Z., & Seok, I. (2021). Modification of coconut shell-based activated carbon and purification of wastewater. Advanced Composites and Hybrid Materials, 4(1), 65–73. https://doi.org/10.1007/s42114-021-00205-4
Ghosh, N., Das, S., Biswas, G., & Haldar, P. K. (2022). Review on some metal oxide nanoparticles as effective adsorbent in wastewater treatment. Water Science and Technology, 85(12), 3370–3395. https://doi.org/10.2166/wst.2022.153
Hossini, H., Shafie, B., Niri, A. D., Nazari, M., Esfahlan, A. J., Ahmadpour, M., Nazmara, Z., Ahmadimanesh, M., Makhdoumi, P., Mirzaei, N., & Hoseinzadeh, E. (2022). A comprehensive review on human health effects of chromium: insights on induced toxicity. Environmental Science and Pollution Research, 29(47), 70686–70705. https://doi.org/10.1007/s11356-022-22705-6
Isharyanti, Sriatun, & Azmiyawati, C. (2024). Adsorpsi ion Cr(III) menggunakan zeolit alam termodifikasi dietanolamin. Greensphere: Journal of Environmental Chemistry, 4(1), 8–13.
Islam, M. M., Mohana, A. A., Rahman, M. A., Rahman, M., Naidu, R., & Rahman, M. M. (2023). A Comprehensive Review of the Current Progress of Chromium Removal Methods from Aqueous Solution. Toxics, 11(3), 1–43. https://doi.org/10.3390/toxics11030252
Juturu, R., Selvaraj, R., & Murty, V. R. (2024). Efficient removal of hexavalent chromium from wastewater using a novel magnetic biochar composite adsorbent. Journal of Water Process Engineering, 66(July). https://doi.org/10.1016/j.jwpe.2024.105908
Kamel, M., Bastaweesy, A. M., & Hefny, R. A. (2025). Optimized Removal of Cr (VI) and Ni (II) From Wastewater Using Corncob-Derived Activated Carbon. Water, Air, and Soil Pollution, 236(2), 1–22. https://doi.org/10.1007/s11270-024-07711-3
Kaushal, A., & Singh, S. K. (2017). Critical analysis of adsorption data statistically. Applied Water Science, 7(6), 3191–3196. https://doi.org/10.1007/s13201-016-0466-4
Kismolo, E., Prayitno, & Nurimaniwathy. (2002). Pengelolaan Limbah Khrom Residu Proses Recovery Khorm Menggunakan Kalsium Karbonat. Prosiding Pertemuan Dan Presentasi Ilmiah Penelitian Dasar Ilmu Pengetahuan Dan Teknologi Nuklir, 1(1), 153–158.
Krawic, C., & Zhitkovich, A. (2023). Chemical mechanisms of DNA damage by carcinogenic chromium(VI). Advances in Pharmacology, 96(0), 25–46. https://doi.org/10.1016/bs.apha.2022.07.003
Lubis, R. Y., Sirait, R., & Fahmijal, I. (2023). Pembuatan Karbon Aktif dari Sabut Kelapa dengan Aktivasi menggunakan H3PO4 untuk Adsorpsi Air Gambut. Journal Online of Physics, 8(2), 23–28.
Mkilima, T., Zharkenov, Y., Abduova, A., Sarypbekova, N., Kudaibergenov, N., Sakanov, K., Zhukenova, G., Omarov, Z., Sultanbekova, P., & Kenzhaliyeva, G. (2024). Utilization of banana peel-derived activated carbon for the removal of heavy metals from industrial wastewater. Case Studies in Chemical and Environmental Engineering, 10(May), 100791. https://doi.org/10.1016/j.cscee.2024.100791
Mohanty, S., Benya, A., Hota, S., Kumar, M. S., & Singh, S. (2023). Eco-toxicity of hexavalent chromium and its adverse impact on environment and human health in Sukinda Valley of India: A review on pollution and prevention strategies. Environmental Chemistry and Ecotoxicology, 5(November 2022), 46–54. https://doi.org/10.1016/j.enceco.2023.01.002
Nurjaibah, A., & Fauziah, N. (2025.). Synthesis of Polyaniline Using the Rapid Mixing Method and Its Utilization as an Adsorbent for Chromium Metal Ions. NPCB, 1–9.
Pet, I., Sanad, M. N., Farouz, M., ElFaham, M. M., El-Hussein, A., El-sadek, M. S. A., Althobiti, R. A., & Ioanid, A. (2024). Review: Recent Developments in the Implementation of Activated Carbon as Heavy Metal Removal Management. Water Conservation Science and Engineering, 9(2), 1–15. https://doi.org/10.1007/s41101-024-00287-3
Purnata, H., Rahmat, S., Ilahi, N. A., & Triwuri, N. A. (2025). Room of Civil Society Development Pengolahan Limbah Cair Batik dengan Elektrokoagulasi dan Filtrasi- Adsorbsi untuk Keberlanjutan. Room of Civil Society Development, 4(1), 197–210.
Qasem, N. A. A., Mohammed, R. H., & Lawal, D. U. (2021). Removal of heavy metal ions from wastewater: a comprehensive and critical revifile:///C:/Users/Windows 11/Downloads/referensi NPCB sabut kelapa/Isharyanti 2024.pdfew. Npj Clean Water, 4(1). https://doi.org/10.1038/s41545-021-00127-0
Rahayu, A. (2023). Review : Biomassa Sebagai Adsorbent untuk Pengolahan Logam Berat Pada Air Limbah Industri. Prosiding Seminar Nasional Teknik Kimia “Kejuangan,” 1–6.
Rivera-Utrilla, J., & Sánchez-Polo, M. (2003). Adsorption of Cr(III) on ozonised activated carbon. Importance of Cπ—cation interactions. Water Research, 37(14), 3335–3340. https://doi.org/10.1016/S0043-1354(03)00177-5
Rout, D. R., & Jena, H. M. (2023). Synthesis of graphene oxide-modified porous chitosan cross-linked polyaniline composite for static and dynamic removal of Cr(VI). Environmental Science and Pollution Research, 30(9), 22992–23011. https://doi.org/10.1007/s11356-022-23774-3
Sánchez, J., Rodriguez, C., Oyarce, E., & Rivas, B. L. (2020). Removal of chromium ions by functional polymers in conjunction with ultrafiltration membranes. Pure and Applied Chemistry, 92(6), 883–896. https://doi.org/10.1515/pac-2019-1103
Saxena, V., Singh, A. K., Srivastava, A., & Srivastava, A. (2024). Eco-Engineered Low-Cost Carbosorbent Derived from Biodegradable Domestic Waste for Efficient Total Chromium Removal from Aqueous Environment: Spectroscopic and Adsorption Study. Nature Environment and Pollution Technology, 23(2), 979–989. https://doi.org/10.46488/NEPT.2024.v23i02.032
Selvi, K., Pattabhi, S., & Kadirvelu, K. (2001). Removal of Cr(VI) from aqueous solution by adsorption onto activated carbon. Bioresource Technology, 80(1), 87–89. https://doi.org/10.1016/S0960-8524(01)00068-2
Sutanto, K. (2017). Penyisihan kromium (Cr) dalam limbah cair industri pelapisan logam dengan proses filtrasi menggunakan membran. Jurnal Teknik Kimia, 12(2), 45–52.
Tarigan, B. S., Rukiah, & Rostika Noviyanti, A. (2021). Komposisi Polialuminium Klorida Dengan Hidroksiapatit Dan Aplikasinya Untuk Pemisahan Ion Kromium Heksavalen. 30(Vi), 26–34.
Tolkou, A. K., Trikalioti, S., Makrogianni, O., Xanthopoulou, M., Deliyanni, E. A., Kyzas, G. Z., & Katsoyiannis, I. A. (2022). Lanthanum Modified Activated Carbon from Coconut Shells for Chromium ( VI ) Removal from Water. Nanomaterials, 12(7), 1–18. https://doi.org/10.3390/nano12071067
Wijaya, R. A., Nakagoe, O., Sano, H., Tanabe, S., & Kamada, K. (2024). Superior comprehensive performance of modified activated carbon as a hexavalent chromium adsorbent. Heliyon, 10(15), e35557. https://doi.org/10.1016/j.heliyon.2024.e35557
Xie, S. (2024). Water contamination due to hexavalent chromium and its health impacts: exploring green technology for Cr (VI) remediation. Green Chemistry Letters and Reviews, 17(1), 1–19. https://doi.org/10.1080/17518253.2024.2356614
Zhang, L., & Zuo, S. (2024). The Significance of Lignocellulosic Raw Materials on the Pore Structure of Activated Carbons Prepared by Steam Activation. Molecules, 29(13), 1–13. https://doi.org/10.3390/molecules29133197
Ziemińska, N., & Doczekalska, B. (2024). Biomass derived activated carbons in wastewater treatment – The aim of metallurgical industry. Desalination and Water Treatment, 318(March), 100320. https://doi.org/10.1016/j.dwt.2024.100320
Downloads
Published
Issue
Section
License
or all articles published in Natural Product Chemistry Bulletin, the copyright is retained by the journal. Articles are published under the terms of Creative Commons Attribution-ShareAlike 4.0 International License (CC-BY-SA 4.0) .
For Authors:
- Any article on the copyright is retained by the author(s).
- The author grants the journal, right of first publication with the work simultaneously licensed under a Creative Commons Attribution License that allows others to share work with an acknowledgment of the work authors and initial publications in this journal.
- Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of published articles of work (eg, post-institutional repository) or publish it in a book, with acknowledgment of its initial publication in this journal.
- Authors are permitted and encouraged to post their work online (e.g., in institutional repositories or on their websites) prior to and during the submission process, as can lead to productive exchanges, as well as earlier and greater citation of published work.
- The article and any associated published material is distributed under the Creative Commons Attribution-ShareAlike 4.0 International License
Download Journal Template







