Study of Glycine Crystal Growth in Chitosan Matrix as a Biopolymer-Based Piezoelectric Sensor Practicum Medium for Physics Education Students

Authors

  • Nurhandayani Nurhandayani STKIP Darud Da’wah wal Irsyad Pinrang https://orcid.org/0009-0004-9531-6610
  • Nurvadillah Angraini STKIP Darud Da’wah wal Irsyad Pinrang https://orcid.org/0009-0002-5472-3442
  • Yusnita Sari Program Studi Fisika, Fakultas Matematika dan Ilmu Pengetahuan Universitas Halu Oleo, Indonesia
  • Nurul Amalia Aris Program Studi Pendidikan Fisika, STKIP Darud Da’wah wal Irsyad Pinrang, Indonesia

DOI:

https://doi.org/10.52434/jpif.v5i2.43326

Keywords:

Biopolymer, cihtosan, Crystal Growth, glycine, Practicum Media

Abstract

This study aims to examine the growth of glycine crystals in a chitosan matrix and its potential as a biopolymer-based piezoelectric sensor laboratory medium for physics education students. The research methodology involved synthesizing chitosan-glycine films using a solution method, then observing the growth and morphology of glycine crystals visually and using simple optical instruments. The results showed that glycine was able to grow in the chitosan matrix with clearly and evenly formed crystal morphology, which was influenced by the interaction between glycine and the chitosan matrix. The resulting film structure was flexible and transparent, making it suitable for use as an observation medium in practical activities. This study was limited to observing crystal growth without measuring electrical properties or piezoelectric response. Practically, the results of this study provide a simple, inexpensive, and environmentally friendly alternative laboratory medium for introducing the concepts of crystal growth and piezoelectric materials. The social implications support sustainable science learning through the use of biopolymer materials in education

References

Bishara, H., & Berger, S. (2018). Polymorphism and piezoelectricity of glycine nano-crystals grown inside alumina nano-pores. Journal of Materials Science, 54, 4619–4625. https://doi.org/10.1007/s10853-018-03211-y

Broadhurst, E., Xu, H., Clabbers, M., Lightowler, M., Nudelman, F., Zou, X., & Parsons, S. (2020). Polymorph evolution during crystal growth studied by 3D electron diffraction. IUCrJ, 7, 5–9. https://doi.org/10.1107/s2052252519016105

Butto, N., Vera, N. C., Díaz-Soler, F., Yazdani-Pedram, M., & Neira-Carrillo, A. (2020). Effect of Chitosan Electrospun Fiber Mesh as Template on the Crystallization of Calcium Oxalate. Crystals. https://doi.org/10.3390/cryst10060453

Cotting, G., Urquidi, O., Besnard, C., Brazard, J., & Adachi, T. (2025). The effect of salt additives on the glycine crystallization pathway revealed by studying one crystal nucleation at a time. Proceedings of the National Academy of Sciences of the United States of America, 122. https://doi.org/10.1073/pnas.2419638122

Guerin, S., Stapleton, A., Chovan, D., Mouras, R., Gleeson, M., McKeown, C., Noor, M., Silien, C., Rhen, F., Kholkin, A., Liu, N., Soulimane, T., Tofail, S., & Thompson, D. (2018). Control of piezoelectricity in amino acids by supramolecular packing. Nature Materials, 17 2, 180–186. https://doi.org/10.1038/nmat5045

Hosseini, E. S., Manjakkal, L., Shakthivel, D., & Dahiya, R. (2020). Glycine-Chitosan-Based Flexible Biodegradable Piezoelectric Pressure Sensor. ACS Applied Materials and Interfaces, 12(8), 9008–9016. https://doi.org/10.1021/acsami.9b21052

Little, L., King, A., Sear, R., & Keddie, J. (2017). Controlling the crystal polymorph by exploiting the time dependence of nucleation rates. The Journal of Chemical Physics, 147 14, 144505. https://doi.org/10.1063/1.4993566

Nicolle, L., Journot, C., & Gerber‐Lemaire, S. (2021). Chitosan Functionalization: Covalent and Non-Covalent Interactions and Their Characterization. Polymers, 13. https://doi.org/10.3390/polym13234118

Nurhandayani, N., Amalia Aris, N., Angraini, N. A., Indira Nurnaifah Idris, I., Fisika, P., Darud Da, S., & wal Irsyad Pinrang, wah. (2025). Efektivitas Strategi Whole Brain Teaching dalam Mengoptimalisasi Hasil Belajar Fisika Siswa Sekolah Menengah Atas. Jurnal Luminous: Riset Ilmiah Pendidikan Fisika, 6(2), 58–67.

Offiler, C., Davey, R., Cruz-Cabeza, A., & Vetter, T. (2025). Investigating Additive Effects on α-Glycine Growth through the Measurement of Facet Specific Growth Rates. Crystal Growth & Design, 25, 1644–1652. https://doi.org/10.1021/acs.cgd.5c00028

Pellis, A., Guebitz, G., & Nyanhongo, G. (2022). Chitosan: Sources, Processing and Modification Techniques. Gels, 8. https://doi.org/10.3390/gels8070393

Rahmani, F., Bouamrane, O. L., Bouabdallah, A. Ben, Atanase, L., Hellal, A., & Apintiliesei, A. N. (2023). Biomimetic Hydroxyapatite Crystals Growth on Phosphorylated Chitosan Films by In Vitro Mineralization Used as Dental Substitute Materials. Polymers, 15. https://doi.org/10.3390/polym15112470

Susanti, S., Ernawati, T., & Erlangga, S. (2022). The Effect of Online Practicum Learning on Concept Understanding of UST Yogyakarta Science Student. Al Hikmah: Journal of Education. https://doi.org/10.54168/ahje.v3i1.99

Yu, S., Wang, Z., Yuanchang, & Xue, F. (2022). Effect of natural polymer additives on crystal form and morphology of clozapine anhydrate and monohydrate. Journal of Molecular Liquids. https://doi.org/10.1016/j.molliq.2022.119985

Zaccone, M., Patel, M., De Brauwer, L., Nair, R., Montalbano, M. L., Monti, M., & Oksman, K. (2022). Influence of Chitin Nanocrystals on the Crystallinity and Mechanical Properties of Poly(hydroxybutyrate) Biopolymer. Polymers, 14. https://doi.org/10.3390/polym14030562

Published

2025-12-27